Selection Rules for Morse Potential
This code models which transitions are allowed in the harmonic oscillator which uses the Morse potential as the potential energy of the system.
function morse(n)
m = 1;
hbarsq = 1;
pts = 250;
k = 1e3;
q = 1;
n=10;
De = 500;
a = 1;
%now account for the delta x and discritize the number of elements in the x vector
%We say that there are some number of points within the x vector
x = linspace(0, 2, pts);
dx = x(2)-x(1);
D2 = -2*eye(pts) + diag(ones(pts-1,1), 1) + diag(ones(pts-1,1),-1);
T = 1/(dx^2)*(-hbarsq/(2*m))*D2;
Vvec=De*(1-exp(-a*(x-1))).^2;
V=diag(Vvec);
H=T+V;
[vecs, vals] = eig(H);
[srtvecs, srtvals] = eigsort(vecs, vals);
k = diag(srtvals);
l = ones(pts, 1);
repvals = l*k';
sc = 100;
shiftvecs = repvals + sc*srtvecs;
transitions=vecs'*(q*diag(x))*vecs;
figure(1);pcolor(abs(transitions(1:n,1:n).^2))
axis square
figure(2);plot(x,shiftvecs(:,1:n),x,Vvec);
axis([-inf inf 0 450]);
end